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John Tyndall's ratio spectrophotometer (drawing from 1861) measured how much infrared radiation was absorbed and emitted by various gases filling its central tube.

The history of the scientific discovery of climate change began in the early 19th century when ice ages and other natural changes in paleoclimate were first suspected and the natural greenhouse effect was first identified. In the late 19th century, scientists first argued that human emissions of greenhouse gases could change Earth's energy balance and climate. The existence of the greenhouse effect, while not named as such, was proposed as early as 1824 by Joseph Fourier. The argument and the evidence were further strengthened by Claude Pouillet in 1827 and 1838. In 1856 Eunice Newton Foote demonstrated that the warming effect of the sun is greater for air with water vapour than for dry air, and the effect is even greater with carbon dioxide.

John Tyndall was the first to measure the infrared absorption and emission of various gases and vapors. From 1859 onwards, he showed that the effect was due to a very small proportion of the atmosphere, with the main gases having no effect, and was largely due to water vapor, though small percentages of hydrocarbons and carbon dioxide had a significant effect. The effect was more fully quantified by Svante Arrhenius in 1896, who made the first quantitative prediction of global warming due to a hypothetical doubling of atmospheric carbon dioxide.

In the 1960s, the evidence for the warming effect of carbon dioxide gas became increasingly convincing. Scientists also discovered that human activities that generated atmospheric aerosols (e.g., "air pollution") could have cooling effects as well (later referred to as global dimming). Other theories for the causes of global warming were also proposed, involving forces from volcanism to solar variation. During the 1970s, scientific understanding of global warming greatly increased. (Full article...) (Full article...)