1,2-Bis(diphenylphosphino)benzene

1,2-Bis(diphenylphosphino)benzene
Names
	Other names o-Phenylenebis[diphenylphosphine
Identifiers
CAS Number	13991-08-7 [ChemSpider];
3D model (JSmol)	Interactive image;
ChemSpider	436234;
PubChem CID	498379;
CompTox Dashboard (EPA)	DTXSID60333306 ;
	InChI InChI=1S/C30H24P2/c1-5-15-25(16-6-1)31(26-17-7-2-8-18-26)29-23-13-14-24-30(29)32(27-19-9-3-10-20-27)28-21-11-4-12-22-28/h1-24H Key: NFRYVRNCDXULEX-UHFFFAOYSA-N;
	SMILES C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3P(C4=CC=CC=C4)C5=CC=CC=C5;
Properties
Chemical formula	C30H24P2
Molar mass	446.470 g·mol−1
Appearance	white solid
Melting point	185–187 °C (365–369 °F; 458–460 K)
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

1,2-Bis(diphenylphosphino)benzene (dppbz) is an organophosphorus compound with the formula C₆H₄(PPh₂)₂ (Ph = C₆H₅). Classified as a diphosphine ligand, it is a common bidentate ligand in coordination chemistry.^[1] It is a white, air-stable solid. ^[2] As a chelating ligand, dppbz is very similar to 1,2-bis(diphenylphosphino)ethylene.

References[edit]

^ Hatakeyama, Takuji; Kondo, Yoshiyuki; Fujiwara, Yu-Ichi; Takaya, Hikaru; Ito, Shingo; Nakamura, Eiichi; Nakamura, Masaharu (2009). "Iron-catalysed fluoroaromatic coupling reactions under catalytic modulation with 1,2-bis(diphenylphosphino)benzene". Chemical Communications (10): 1216–1218. doi:10.1039/B820879D. PMID 19240878.
^ Csákÿ, Aurelio G.; Molina, María Teresa (2011). "1,2-Bis(diphenylphosphino)benzene". Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rn01300. ISBN 978-0471936237.